Introductory Chemistry  © David W. Ball ; contributors: Maria Pugacheva, Maria del Mar Jimenez Quesada, Oi Mi Lam, George Roungos et al. Source: Flat World Knowledge

 


Chapter 3
Section B
Molecules and Chemical Nomenclature

Molecules and Chemical Nomenclature

Learning Objectives

  1. Define molecule .

  2. Name simple molecules based on their formulas.

  3. Determine the formula of a molecule based on its name.

There are many substances that exist as two or more atoms connected together so strongly that they behave as a single particle. These multi-atom combinations are called molecules. A molecule is the smallest part of a substance that has the physical and chemical properties of that substance. In some respects, a molecule is similar to an atom. A molecule, however, is composed of more than one atom.

Some elements exist naturally as molecules. For example, hydrogen and oxygen exist as two-atom (diatomic) molecules. There are other elements which also exist naturally as diatomic molecules as given in Table 3.3. below. As with any molecule, these elements are labelled with a molecular formula. A molecular formula indicates the number and types of atoms in a molecule. (Sometimes only the word formula is used, and its meaning is inferred from the context.) For example, the molecular formula for elemental hydrogen is H 2 , with H being the symbol for hydrogen and the subscript 2 implying that there are two atoms of this element in the molecule. Other diatomic elements have similar formulas: O 2 , N 2 , and so forth. Of course, there are other elements that exist as molecules with more than two atoms - for example, sulfur normally exists as an eight-atom molecule, S 8 , while phosphorus exists as a four-atom molecule, P 4 (see Figure 3.3. “Molecular Art of S 8 and P 4 Molecules”). Otherwise, we will assume that elements exist as individual atoms, rather than as part of molecules. It is assumed that there is only one atom in a formula if there is no numerical subscript on the right side of an element's symbol.

Table 3.3. Elements That Exist as Diatomic Molecules

Hydrogen
Oxygen
Nitrogen
Fluorine
Chlorine
Bromine
Iodine


Figure 3.3. Molecular Art of S 8 and P 4 Molecules


If each green ball represents a sulfur atom, then the diagram on the left represents an S 8 molecule. The molecule on the right shows that one form of elemental phosphorus exists as a four-atom molecule.


Figure 3.3. “Molecular Art of S 8 and P 4 Molecules” shows two examples of how we will be representing molecules in this text. An atom is represented by a small ball or sphere, which generally indicates where the nucleus is in the molecule. A cylindrical line connecting the balls represents the connection between the atoms that make this collection of atoms a molecule. This connection is called a chemical bond. In Chapter 9 “Chemical Bonds” , we will explore the nature of chemical bonds. You will see other examples of this “ball and cylinder” representation of molecules throughout this book.

Many compounds exist as molecules. In particular, when nonmetals connect with other nonmetals, the compound typically exists as molecules. (Compounds between a metal and a nonmetal are different and will be considered in Chapter 3, Section 4 “Ions and Ionic Compounds” .) Furthermore, in some cases there are many different kinds of molecules that can be formed between any given elements, with all the different molecules having different chemical and physical properties. How do we tell them apart?

The answer is a very specific system of naming compounds, called chemical nomenclature. By following the rules of nomenclature, each and every compound has its own unique name and each name refers specifically to that compound only. Here, we will start with relatively simple molecules that have only two elements in them, the so-called binary compounds :

  1. Identify the elements in the molecule from its formula. This is why you need to know the names and symbols of the elements in Table 3.2. “Names and Symbols of Common Elements”.

  2. Begin the name with the element name of the first element. If there is more than one atom of this element in the molecular formula, use a numerical prefix to indicate the number of atoms, as listed in Table 3.4. “Numerical Prefixes Used in Naming Molecular Compounds”. Do not use the prefix mono- if there is only one atom of the first element.

    Table 3.4. Numerical Prefixes Used in Naming Molecular Compounds

    The Number of Atoms of an Element Prefix
    1 mono-
    2 di-
    3 tri-
    4 tetra-
    5 penta-
    6 hexa-
    7 hepta-
    8 octa-
    9 nona-
    10 deca-


  3. Name the second element by using three pieces:

    1. a numerical prefix indicating the number of atoms of the second element, plus

    2. the stem of the element name (e.g., ox for oxygen, chlor for chlorine, etc.), plus

    3. the suffix -ide .

  4. Combine the two words, leaving a space between them.

Let us see how these steps work for a molecule whose molecular formula is SO 2 , which has one sulfur atom and two oxygen atoms - this completes step 1. According to step 2, we start with the name of the first element - sulfur. Remember, we don't use the mono- prefix for the first element. Now for step 3, we combine the numerical prefix di- (see Table 3.4. “Numerical Prefixes Used in Naming Molecular Compounds”) with the stem ox- and the suffix -ide , to make dioxide . Bringing these two words together, we have the unique name for this compound - sulfur dioxide.

Why all this trouble? There is another common compound consisting of sulfur and oxygen whose molecular formula is SO 3 , so the compounds need to be distinguished. SO 3 has three oxygen atoms in it, so it is a different compound with different chemical and physical properties. The system of chemical nomenclature is designed to give this compound its own unique name . Its name, if you go through all the steps, is sulfur trioxide. Different compounds have different names.

In some cases, when a prefix ends in a or o and the element name begins with o we drop the a or o on the prefix. So we see monoxide or pentoxide rather than monooxide or pentaoxide in molecule names.

One great thing about this system is that it works both ways. From the name of a compound, you should be able to determine its molecular formula. Simply list the element symbols, with a numerical subscript if there is more than one atom of that element, in the order of the name (we do not use a subscript 1 if there is only one atom of the element present; 1 is implied). From the name nitrogen trichloride , you should be able to get NCl 3 as the formula for this molecule. From the name diphosphorus pentoxide , you should be able to get the formula P 2 O 5 (note the numerical prefix on the first element, indicating there is more than one atom of phosphorus in the formula).

Example 3

Name each molecule.

  1. PF 3

  2. CO

  3. Se 2 Br 2

Solution

  1. A molecule with a single phosphorus atom and three fluorine atoms is called phosphorus trifluoride.

  2. A compound with one carbon atom and one oxygen atom is properly called carbon monoxide, not carbon monooxide.

  3. There are two atoms of each element, selenium and bromine. According to the rules, the proper name here is diselenium dibromide .

Test Yourself

Name each molecule.

  1. SF 4

  2. P 2 S 5

Solution

  1. Sulfur tetrafluoride

  2. Diphosphorus pentasulfide

Example 4

Give the formula for each molecule.

  1. Carbon tetrachloride

  2. Silicon dioxide

  3. Trisilicon tetranitride

Solution

  1. The name carbon tetrachloride implies one carbon atom and four chlorine atoms, so the formula is CCl 4 .

  2. The name silicon dioxide implies one silicon atom and two oxygen atoms, so the formula is SiO 2 .

  3. We have a name that has numerical prefixes on both elements. Tri- means three, and tetra- means four, so the formula of this compound is Si 3 N 4 .

Test Yourself

Give the formula for each molecule.

  1. Disulfur difluoride

  2. Iodine pentabromide

Solution

  1. S 2 F 2

  2. IBr 5

Some simple molecules have common names that we use as part of the formal system of chemical nomenclature. For example, H 2 O is given the name water , not dihydrogen monoxide . NH 3 is called ammonia , while CH 4 is called methane . We will occasionally see other molecules that have common names; we will point them out as they occur.

Key Takeaways

  • Molecules are groups of atoms that behave as a single unit.

  • Some elements exist as molecules: hydrogen, oxygen, sulfur, and so forth.

  • There are rules that express a unique name for any given molecule, and a unique formula for any given name.

Exercises

1. Which of these formulas represent molecules? State how many atoms are in each molecule.
  1. Fe
  2. PCl 3
  3. P 4
  4. Ar
  1. not a molecule
  2. a molecule; four atoms total
  3. a molecule; four atoms total
  4. not a molecule
2. Which of these formulas represent molecules? State how many atoms are in each molecule.
  1. I 2
  2. He
  3. H 2 O
  4. Al
  1. molecule; two atoms
  2. not a molecule
  3. molecule; three atoms
  4. not a molecule
3. What is the difference between CO and Co?
CO is a compound of carbon and oxygen; Co is the element cobalt.

4. What is the difference between H 2 O and H 2 O 2 (hydrogen peroxide)?
The first molecule has one oxygen atom, while the second molecule has two oxygen atoms. The first molecule is water, while the second molecule is hydrogen peroxide.

5. Give the proper formula for each diatomic element.
H 2 , O 2 , N 2 , F 2 , Cl 2 , Br 2 , I 2

6. In 1986, when Halley's comet last passed the earth, astronomers detected the presence of S 2 in their telescopes. Why is sulfur not considered a diatomic element?
S 2 is not a stable form of elemental sulfur.

7. What is the stem of fluorine used in molecule names? CF 4 is one example.
fluor-

8. What is the stem of selenium used in molecule names? SiSe 2 is an example.
selen-

9. Give the proper name for each molecule.
  1. PF 3
  2. TeCl 2
  3. N 2 O 3
  1. Phosphorus trifluoride
  2. Tellurium dichloride
  3. Dinitrogen trioxide
10. Give the proper name for each molecule.
  1. NO
  2. CS 2
  3. As 2 O 3
  1. Nitrogen monoxide
  2. Carbon disulfide
  3. Diarsenic trioxide
11. Give the proper name for each molecule.
  1. XeF 2
  2. O 2 F 2
  3. SF 6
  1. Xenon difluoride
  2. Dioxygen difluoride
  3. Sulfur hexafluoride
12. Give the proper name for each molecule.
  1. P 4 O 10
  2. B 2 O 3
  3. P 2 S 3
  1. Tetraphosphorus decoxide
  2. Diboron trioxide
  3. Diphosphorus trisulfide
13. Give the proper name for each molecule.
  1. N 2 O
  2. N 2 O 4
  3. N 2 O 5
  1. Dinitrogen monoxide
  2. Dinitrogen tetroxide
  3. Dinitrogen pentoxide
14. Give the proper name for each molecule.
  1. SeO 2
  2. Cl 2 O
  3. XeF 6
  1. Selenium dioxide
  2. Dichlorine monoxide
  3. Xenon hexafluoride
15. Give the proper formula for each name.
  1. Dinitrogen pentoxide
  2. Tetraboron tricarbide
  3. Phosphorus pentachloride
  1. N 2 O 5
  2. B 4 C 3
  3. PCl 5
16. Give the proper formula for each name.
  1. Nitrogen triiodide
  2. Diarsenic trisulfide
  3. Iodine trichloride
  1. NI 3
  2. As 2 S 3
  3. ICl 3
17. Give the proper formula for each name.
  1. Dioxygen dichloride
  2. Dinitrogen trisulfide
  3. Xenon tetrafluoride
  1. O 2 Cl 2
  2. N 2 S 3
  3. XeF 4
18. Give the proper formula for each name.
  1. Chlorine dioxide
  2. Selenium dibromide
  3. Dinitrogen trioxide
  1. ClO 2
  2. SeBr 2
  3. N 2 O 3
19. Give the proper formula for each name.
  1. Iodine trifluoride
  2. Xenon trioxide
  3. Disulfur decafluoride
  1. IF 3
  2. XeO 3
  3. S 2 F 10
20. Give the proper formula for each name.
  1. Germanium dioxide
  2. Carbon disulfide
  3. Diselenium dibromide
  1. GeO 2
  2. CS 2
  3. Se 2 Br 2

If you wish to have a tutorial, discussion, or question & answer session on this course topics with Dr Huei-Nin Liu-Johnson (PEOI's faculty #103834, PhD Yale University) you are welcome to email your request to hnliujohnson@gmail.com . PEOI's interactive learning is free of charge to registered students, and registration is also free.

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Prior Atomic Theory Modified: 2023 Next Masses of Atoms and Molecules