Introductory Chemistry  © David W. Ball ; contributors: Hawar Haider, Maria del Mar Jimenez Quesada, Tatyana Sobolyeva, Oi Mi Lam et al. Source: Flat World Knowledge

 


Chapter 3
Section A
Atomic Theory

Atomic Theory

Learning Objectives

  1. State the modern atomic theory.

  2. Learn the structure of the atom.

The smallest component of an element that uniquely defines the identity of that element is called an atom . Individual atoms are extremely small. It would take about fifty million atoms in a row to make a line that is 1 cm long. The period at the end of a printed sentence has several million atoms in it.

The concept that atoms play a fundamental role in chemistry is formalized by the modern atomic theory , first proposed by John Dalton, an English scientist, in 1803. It consists of three parts:

  1. All matter is made up of atoms. Atoms cannot be divided, created or destroyed

  2. All atoms of the same element are identical. Different elements have different types of atoms

  3. Chemical reactions occur when atoms are rearranged. Compounds are formed from atoms of the constituent elements.

These concepts form the basis of chemistry.

Although the word atom comes from a Greek word that means indivisible, we understand now that atoms themselves are composed of smaller parts called subatomic particles . The first part to be discovered was the electron , a tiny subatomic particle with a negative charge. It is often represented as e - , with the right superscript showing the negative charge. Later, two larger particles were discovered. The proton is a larger (but still tiny) subatomic particle with a positive charge, represented as p + . The neutron is a subatomic particle with about the same mass as a proton but no charge. It is represented as either n or n 0 . We now know that all atoms of all elements are composed of electrons, protons, and (with one exception) neutrons. Table 3.1 summarizes the properties of these three subatomic particles.

Table 3.1. Properties of the Three Subatomic Particles

Name Symbol Mass (approx.; kg) Charge
Proton p + 1.6 x 10 -27 1+
Neutron n, n 0 1.6 x 10 -27 none
Electron e - 9.1 x 10 -31 1-


Later in 1910, experiments by Ernest Rutherford in England pointed to a nuclear model of the atom. The relatively massive protons and neutrons are collected in the center of the atom, in a very small region called the nucleus of the atom (plural nuclei ). The electrons are rotating in shells orbiting the nucleus. (See Figure 3.1. The Structure of the Atom .)

Figure 3.1. The Structure of the Atom


Atoms have protons and neutrons in the center, making the nucleus positively charged, while the negatively charged electrons orbit the nucleus.


The modern atomic theory states that atoms of one element are the same, while atoms of different elements are different. What makes atoms of different elements different? The fundamental characteristic that all atoms of the same element share is the number of protons . All atoms of hydrogen have one and only one proton in the nucleus; all atoms of iron have 26 protons in the nucleus. This number of protons is so important to the identity of an atom that it is called the atomic number of the element. Thus, hydrogen has an atomic number of 1, while iron has an atomic number of 26. Each element has its own characteristic atomic number.

However, atoms of the same element can have different numbers of neutrons. Atoms of the same element (i.e., atoms with the same number of protons) with different numbers of neutrons are called isotopes . Most naturally occurring elements exist as isotopes. For example, most hydrogen atoms have a single proton in their nucleus. However, a small number (about one in a million) of hydrogen atoms have a proton and a neutron in their nuclei. This particular isotope of hydrogen is called deuterium. A very rare form of hydrogen has one proton and two neutrons in the nucleus; this isotope of hydrogen is called tritium. The sum of the number of protons and neutrons in the nucleus is called the mass number of the isotope.

In a neutral atom the number of electrons equals the number of protons, so the overall charge of an atom is zero.

Example 1

  1. The most common carbon atoms have six protons and six neutrons in their nuclei. What are the atomic number and the mass number of these carbon atoms?

  2. An isotope of uranium has an atomic number of 92 and a mass number of 235. What are the number of protons and neutrons in the nucleus of this atom?

Solution

  1. If a carbon atom has six protons in its nucleus, its atomic number is 6. If it also has six neutrons in the nucleus, then the mass number is 6 +6, or 12.

  2. If the atomic number of uranium is 92, then that is the number of protons in the nucleus. Because the mass number is 235, then the number of neutrons in the nucleus is 235-92, or 143.

Test Yourself

The number of protons in the nucleus of a tin atom is 50, while the number of neutrons in the nucleus is 68. What are the atomic number and the mass number of this isotope?

Answer

Atomic number = 50, mass number = 118

When referring to an atom, we simply use the element's name: the term sodium refers to the element as well as an atom of sodium. But it can be unwieldy to use the name of elements all the time. Instead, chemistry defines a symbol for each element. The atomic symbol is a one- or two-letter abbreviation of the name of the element. By convention, the first letter of an element's symbol is always capitalized, while the second letter (if present) is lowercase. Thus, the symbol for hydrogen is H, the symbol for sodium is Na, and the symbol for nickel is Ni. Most symbols come from the English name of the element, although some symbols come from an element's Latin name. (The symbol for Sodium, Na, comes from its Latin name, Natrium .) Table 3.2.lists some common elements and their symbols. You should memorize the symbols in Table 3.2. Names and Symbols of Common Elements , as this is how we will be representing elements throughout chemistry.

Table 3.2. Names and Symbols of Common Elements

Element Name Symbol   Element Name Symbol
Aluminum Al   Mercury Hg
Argon Ar Molybdenum Mo
Arsenic As Neon Ne
Barium Ba Nickel Ni
Beryllium Be Nitrogen N
Bismuth Bi Oxygen O
Boron B Palladium Pd
Bromine Br Phosphorus P
Calcium Ca Platinum Pt
Carbon C Potassium K
Chlorine Cl Radium Ra
Chromium Cr Radon Rn
Cobalt Co Rubidium Rb
Copper Cu Scandium Sc
Fluorine F Selenium Se
Gallium Ga Silicon Si
Germanium Ge Silver Ag
Gold Au Sodium Na
Helium He Strontium Sr
Hydrogen H Sulfur S
Iodine I Tantalum Ta
Iridium Ir Tin Sn
Iron Fe Titanium Ti
Krypton Kr Tungsten W
Lead Pb Uranium U
Lithium Li Xenon Xe
Magnesium Mg Zinc Zn
Manganese Mn Zirconium Zr


The elements are grouped together in a special chart called the Periodic Table . A simple Periodic Table is shown in Figure 3.2 , while a more extensive one is presented in Chapter 17, Appendix: Periodic Table of the Elements . The elements on the periodic table are listed in order of ascending atomic number. The periodic table has a special shape that will become important to us when we consider the organization of electrons in atoms (see

Figure 3.2. A Simple Periodic Table


There is an easy way to represent isotopes using the atomic symbols. We use the construction

where X is the symbol of the element, A is the mass number, and Z is the atomic number. Thus, for the isotope of carbon that has 6 protons and 6 neutrons, the symbol is

where C is the symbol for the element, 6 represents the atomic number, and 12 represents the mass number.

Example 2

  1. What is the symbol for an isotope of uranium that has an atomic number of 92 and a mass number of 235?

  2. What is the atom with the symbol Fe? Can you tell the numbers of protons and neutrons in this atom?

Solution

  1. .

  2. This is an iron atom. It has 26 protons and 56-26 = 30 neutrons.

Test Yourself

How many protons are there in this Sodium atom?

Answer

11 protons

It is also common to state the mass number after the name of an element to indicate a particular isotope. Carbon-12 represents an isotope of carbon with 6 protons and 6 neutrons, while uranium-238 is an isotope of uranium that has 146 neutrons.

Key Takeaways

  • Chemistry is based on the modern atomic theory, which states that all matter is composed of atoms.

  • Atoms are composed of protons, neutrons, and electrons.

  • Each element has its own atomic number, which is equal to the number of protons in its nucleus.

  • Isotopes of an element contain different numbers of neutrons.

  • Elements are represented by an atomic symbol.

  • The periodic table is a chart that organizes all the elements.

Exercises

1. List the three statements that make up the modern atomic theory.
All matter is composed of atoms; atoms of the same element are the same, and atoms of different elements are different; atoms combine in whole-number ratios to form compounds.

2. Explain the structure of the atom.
Atoms have protons and neutrons together at the center of an atom (the nucleus), and electrons orbit around the nucleus.

3. Which is larger, a proton or an electron?
A proton is larger than an electron.

4. Which is larger, a neutron or an electron?
A neutron is larger than an electron.

5. What are the charges for each of the three subatomic particles?
proton: 1+; electron: 1-; neutron: 0

6. Where is most of the mass of an atom located?
Most of the mass of an atom is located in the nucleus.

7. Sketch a diagram of a boron atom, which has five protons and six neutrons in its nucleus.
8. Sketch a diagram of a helium atom, which has two protons and two neutrons in its nucleus.
9. Define atomic number . What is the atomic number for a boron atom?
The atomic number is the number of protons in a nucleus. Boron has an atomic number of five.

10. What is the atomic number of helium?
The atomic number of helium is two.

11. Define isotope and give an example.
are examples. Isotopes are atoms with the same numbers of protons (atomic number) but different numbers of neutrons (atomic mass).

12. What is the difference between deuterium and tritium?
Deuterium has one neutron in the nucleus, and tritium has two neutrons.

13. Which pair represents isotopes?
  1. isotopes
  2. not isotopes

  3. not isotopes

14. Which pair represents isotopes?
  1. not isotopes
  2. isotopes

  3. isotopes

15. Give a complete symbol for each atom, including the atomic number and the mass number.
  1. an oxygen atom with 8 protons and 8 neutrons
  2. a potassium atom with 19 protons and 20 neutrons
  3. a lithium atom with 3 protons and 4 neutrons
16. Give a complete symbol for each atom, including the atomic number and the mass number.
  1. a magnesium atom with 12 protons and 12 neutrons
  2. a magnesium atom with 12 protons and 13 neutrons
  3. a xenon atom with 54 protons and 77 neutrons
17. Americium-241 is an isotope used in smoke detectors. What is the complete symbol for this isotope?

18. Carbon-14 is an isotope used to perform radioactive dating tests on previously living material. What is the complete symbol for this isotope?

19. Give the atomic symbol for each element.
  1. sodium
  2. argon
  3. nitrogen
  4. radon
  1. Na
  2. Ar
  3. N
  4. Rn
20. Give the atomic symbol for each element.
  1. silver
  2. gold
  3. mercury
  4. iodine
  1. Ag
  2. Au
  3. Hg
  4. I
21. Give the name of the element.
  1. Si
  2. Mn
  3. Fe
  4. Cr
  1. silicon
  2. manganese
  3. iron
  4. chromium
22. Give the name of the element.
  1. F
  2. Cl
  3. Br
  4. I
  1. fluorine
  2. chlorine
  3. bromine
  4. iodine

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